Issue 20, 2008
From the journal:

Chemical Communications

Spectral observation of conversion between ionized vs. non-ionized proton-coupled electron transfer interfaces†

Elizabeth R. Young,a   Joel Rosenthala  and  Daniel G. Noceraa  

a Department of Chemistry, 6-335, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, USA
E-mail: nocera@mit.edu
Fax: 01 617 253 7670
Tel: 01 617 253 5537

Abstract

Two-point hydrogen bonding between acid and base functionalities provides a convenient method for the modular assembly of proton-coupled electron transfer (PCET) networks, especially when that interface comprises an amidinium and two-point anionic partner; a system is presented that permits the proton configuration within the interface to be determined when pKa values of the conjugate acids are known.

Graphical abstract: Spectral observation of conversion between ionized vs. non-ionized proton-coupled electron transfer interfaces

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Article information

DOI
https://doi.org/10.1039/B717747J
Article type
Communication
Submitted
15 Nov 2007
Accepted
29 Feb 2008
First published
14 Apr 2008

Chem. Commun., 2008, 2322-2324

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Spectral observation of conversion between ionized vs. non-ionized proton-coupled electron transfer interfaces

E. R. Young, J. Rosenthal and D. G. Nocera, Chem. Commun., 2008, 2322 DOI: 10.1039/B717747J

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