Issue 7, 2006

Interactions and two-phase coexistence in nonionic micellar solutions as determined by static light scattering

Abstract

We suggest semi-phenomenological approaches for the pair interaction potential in aqueous CmEn solutions. These expressions are non-linear least squares fitted to static light scattering data from solutions of CmE4 and CmE8 surfactants in the long wavelength limit. From the resulting interaction parameters we calculate the location of the liquid/liquid two phase coexistence curves, which are in very good agreement with experimental data reported by others.

Graphical abstract: Interactions and two-phase coexistence in nonionic micellar solutions as determined by static light scattering

Article information

Article type
Paper
Submitted
16 Sep 2005
Accepted
22 Nov 2005
First published
09 Dec 2005

Phys. Chem. Chem. Phys., 2006,8, 869-876

Interactions and two-phase coexistence in nonionic micellar solutions as determined by static light scattering

D. Kleshchanok, H. Strunk, R. Tuinier and P. R. Lang, Phys. Chem. Chem. Phys., 2006, 8, 869 DOI: 10.1039/B513225H

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