Issue 2, 1985
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and structural assessment of ammonium and caesium difluorodioxoperoxouranates(VI), A2[UO2(O2)F2](A = NH4 or Cs), and alkali-metal difluorodioxoperoxouranate(VI) monohydrates, A2[UO2(O2)F2]·H2O (A = K or Rb)

Manabendra N. Bhattacharjee,   Mihir K. Chaudhuri  and  Ranendra N. Dutta Purkayastha  

Abstract

The product obtained by treating an aqueous solution of UO2(NO3)2·6H2O with NH4OH or KOH reacts with AF (A = NH4, Rb, or Cs) or KF, 30% H2O2, and a very small amount of 40% HF, in the mol ratio UO2(NO3)2·6H2O:AF:H2O2 of 1:4:110.8, at pH 6.5–7 to afford ammonium and caesium difluorodioxoperoxouranates(VI), A2[UO2(O2) F2](A = NH4 or Cs), and potassium and rubidium difluorodioxoperoxouranate(VI) monohydrates, A2[UO2(O2)F2]·H2O (A = K or Rb). The i.r. spectra suggest that the peroxo-ligand is bonded to the UO22+ centre in a triangular bidentate (C2v,) manner.

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Article information

DOI
https://doi.org/10.1039/DT9850000409
Article type
Paper

J. Chem. Soc., Dalton Trans., 1985, 409-411

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Synthesis and structural assessment of ammonium and caesium difluorodioxoperoxouranates(VI), A2[UO2(O2)F2](A = NH4 or Cs), and alkali-metal difluorodioxoperoxouranate(VI) monohydrates, A2[UO2(O2)F2]·H2O (A = K or Rb)

M. N. Bhattacharjee, M. K. Chaudhuri and R. N. D. Purkayastha, J. Chem. Soc., Dalton Trans., 1985, 409 DOI: 10.1039/DT9850000409

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