Issue 23, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, structural and magnetic characterisation of a new Mn–Gd pivalate: preparation from a pre-formed hexanuclear cluster †

Cristiano Benelli,   Mark Murrie,   Simon Parsons  and  Richard E. P. Winpenny  

Abstract

The synthesis and crystal structures of two isostructural Mn(III)Ln(III) pivalates (Ln = Gd, Dy) are reported; magnetic data are presented for [Mn2Gd2O2(O2CCMe3)8(HO2CCMe3)2(MeOH)2], the susceptibility behaviour being dominated by strong antiferromagnetic coupling between the di-µ-oxo-bridged Mn(III) centres; this complex represents the first reported example of ferromagnetic coupling between Mn and Gd in a discrete polynuclear complex.

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Article information

DOI
https://doi.org/10.1039/A907977G
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 4125-4126

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Synthesis, structural and magnetic characterisation of a new Mn–Gd pivalate: preparation from a pre-formed hexanuclear cluster †

C. Benelli, M. Murrie, S. Parsons and R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1999, 4125 DOI: 10.1039/A907977G

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