Issue 4, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Heterocyclic phosphorus ligands from cluster-bonded allenylidene

Michael I. Bruce,a   Brian W. Skelton,b   Allan H. Whiteb  and  Natasha N. Zaitsevaa  

a Department of Chemistry, University of Adelaide, Adelaide, Australia
E-mail: michael.bruce@adelaide.edu.au

b Department of Chemistry, University of Western Australia, Nedlands, Australia

Abstract

The reactions between dppm or dppe and Ru3(μ-H){μ3-C2CH2(OH)}(CO)9 in the presence of HBF4·OMe2 afford complexes containing novel diphosphacycloalkyne ligands, formed by double nucleophilic attack of the di-tertiary phosphine on an intermediate allenylidene complex.

Graphical abstract: Heterocyclic phosphorus ligands from cluster-bonded allenylidene

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Article information

DOI
https://doi.org/10.1039/B100661O
Article type
Communication
Submitted
21 Nov 2000
Accepted
17 Jan 2001
First published
26 Jan 2001

J. Chem. Soc., Dalton Trans., 2001, 355-356

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Heterocyclic phosphorus ligands from cluster-bonded allenylidene

M. I. Bruce, B. W. Skelton, A. H. White and N. N. Zaitseva, J. Chem. Soc., Dalton Trans., 2001, 355 DOI: 10.1039/B100661O

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