Issue 2, 2003
From the journal:

Dalton Transactions

Structural control of metalloporphyrinogens by macrocycle modification: steric blocking of the macrocyclic cavity through trans-N,N′-dimethylation

Jun Wang,a   Michael G. Gardiner,*a   Evan J. Peacock,b   Brian W. Skeltonc  and  Allan H. Whitec  

* Corresponding authors

a School of Chemistry, University of Tasmania, Private Bag 75, Hobart, TAS, 7001, Australia
E-mail: Michael.Gardiner@utas.edu.au;

b Central Science Laboratory, University of Tasmania, Private Bag 74, Hobart, TAS, 7001, Australia

c Chemistry Department, University of Western Australia, Crawley, WA, 6009, Australia

Abstract

Reactions of potassium metal with trans-N,N′-dimethyl-meso-octaethylporphyrinogen or meso-octaethyldioxaporphyrinogen afford dipotassium complexes with one potassium cation excluded from the cavity on steric grounds in the former case, or both potassium cations bound inside the macrocyclic cavity in the latter case.

Graphical abstract: Structural control of metalloporphyrinogens by macrocycle modification: steric blocking of the macrocyclic cavity through trans-N,N′-dimethylation

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Article information

DOI
https://doi.org/10.1039/B210600K
Article type
Communication
Submitted
28 Oct 2002
Accepted
02 Dec 2002
First published
11 Dec 2002

Dalton Trans., 2003, 161-162

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Structural control of metalloporphyrinogens by macrocycle modification: steric blocking of the macrocyclic cavity through trans-N,N′-dimethylation

J. Wang, M. G. Gardiner, E. J. Peacock, B. W. Skelton and A. H. White, Dalton Trans., 2003, 161 DOI: 10.1039/B210600K

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