Issue 10, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

Studies on metal carboxylates. Part IV. Pyridine-2,6-dicarboxylate complexes of cobalt(II), nickel(II), rhodium(II), and rhodium(III). Synthesis, spectral and magnetic properties, and a study of rhodium 3d binding energies by X-ray photoelectron spectroscopy

Raymond W. Matthews,   Anthony D. Hamer,   David L. Hoof,   David G. Tisley  and  Richard A. Walton  

Abstract

The synthesis and characterization of the 1 : 1 and 1 : 2 complexes of cobalt(II) and nickel(II) with pyridine-2,6-dicarboxylic acid (dpcH2) are reported. The 1 : 2 complexes are shown to have the structure M(dpcH)2,3H2O, containing monoanionic terdentate dpcH ligand molecules, with three molecules of ‘lattice’ water, whereas the 1 : 1 complexes M(dpc),3H2O are six-co-ordinate and contain co-ordinated water. Anhydrous polymeric [Co-(dpc)]n has been prepared and its chemical reactivity investigated. Rhodium(II) acetate reacts with dpcH2 to afford a rhodium(II) complex Rh(dpc),3H2O. The rhodium(III) complexes Na[Rh(dpc)2],2H2O and Ph4As-[Rh(dpc)2],xH2O have also been prepared. Characterization of the rhodium complexes has included a study of their X-ray photoelectron spectra and a measurement of the rhodium 3d3/2 and 3d5/2 binding energies.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9730001035
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 1035-1038

Permissions

Request permissions

Studies on metal carboxylates. Part IV. Pyridine-2,6-dicarboxylate complexes of cobalt(II), nickel(II), rhodium(II), and rhodium(III). Synthesis, spectral and magnetic properties, and a study of rhodium 3d binding energies by X-ray photoelectron spectroscopy

R. W. Matthews, A. D. Hamer, D. L. Hoof, D. G. Tisley and R. A. Walton, J. Chem. Soc., Dalton Trans., 1973, 1035 DOI: 10.1039/DT9730001035

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements