Issue 8, 1981
From the journal:

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Optical activity of rare earth crystals. Europium oxydiacetate

Asok Chandra Sen,   Mihir Chowdhury  and  Robert W. Schwartz  

Abstract

The circular dichroism (c.d.) spectra corresponding to 7F0→5D1.2 and 7F1→5D0,1,2 transitions of the europium oxydiacetate crystal are reported. The electric dipole and magnetic dipole contributions to the total transition moment are separated for the principally magnetic dipole allowed 7F0→5D1 transition as well as for the principally electric dipole allowed 7F0→5D2 transition. C.d. spectroscopy is shown to be a particularly sensitive technique for observing 7F1→5D1, 5D2 transitions. A calculation correlating c.d. spectra and structure, the first of its kind for lanthanide complexes, is attempted with the Judd–Ofelt model as basis.

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Article information

DOI
https://doi.org/10.1039/F29817701293
Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1981,77, 1293-1300

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Optical activity of rare earth crystals. Europium oxydiacetate

A. C. Sen, M. Chowdhury and R. W. Schwartz, J. Chem. Soc., Faraday Trans. 2, 1981, 77, 1293 DOI: 10.1039/F29817701293

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