Issue 4, 2006
From the journal:

Green Chemistry

In situ generation of hydrogen for continuous hydrogenation reactions in high temperature water

Eduardo Garcia-Verdugo,†*a   Zhimin Liu,‡a   Eliana Ramirez,§a   Juan Garcia-Serna,a   Joan Fraga-Dubreuil,a   Jason R. Hyde,a   Paul A. Hamleya  and  Martyn Poliakoff*a  

* Corresponding authors

a School of Chemistry, University Park, Nottingham, UK
E-mail: martyn.poliakoff@nottingham.ac.uk
Fax: +44 (0)115 951 3058
Tel: +44 (0)115 951 3520

Abstract

The thermal decomposition of HCO2H or preferably, HCO2X (X = Na or NH4) can be used to generate H2 for the continuous hydrogenation of aromatic and cyclic aldehydes, ketones and nitroaromatics in high temperature pressurised water (HTPW). This means that hydrogenation reactions can be carried out in exactly the same equipment as has previously been used for selective oxidation in HTPW, thus facilitating relatively simple application of these reactions for non-specialists.

Graphical abstract: In situ generation of hydrogen for continuous hydrogenation reactions in high temperature water

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Article information

DOI
https://doi.org/10.1039/B515470G
Article type
Paper
Submitted
31 Oct 2005
Accepted
22 Dec 2005
First published
31 Jan 2006

Green Chem., 2006,8, 359-364

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In situ generation of hydrogen for continuous hydrogenation reactions in high temperature water

E. Garcia-Verdugo, Z. Liu, E. Ramirez, J. Garcia-Serna, J. Fraga-Dubreuil, J. R. Hyde, P. A. Hamley and M. Poliakoff, Green Chem., 2006, 8, 359 DOI: 10.1039/B515470G

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