Issue 13, 2008

Efficient photosensitized energy transfer and near-IR fluorescence from porphyrin–SWNT complexes

Abstract

Energy transfer from photoexcited porphyrin molecules to single-walled carbon nanotubes (SWNTs) has been experimentally detected for samples in aqueous Triton X-100 micellar suspensions. Addition of SWNTs to micelle-suspended porphyrin results in strong quenching of porphyrin fluorescence. Measurements of concentration-dependent quenching and spectra suggest that this process arises from formation of ground state non-covalent complexes between porphyrins and SWNTs. Optical excitation of the porphyrin generates characteristic near-IR emission from the SWNTs, indicating efficient energy transfer within the complexes. This energy transfer is deduced to occur through a Dexter-type electron exchange mechanism. Complexation of SWNTs with organic photosensitizers provides a novel way of uniformly exciting a wide range of nanotube structural species in polydisperse samples using only a single excitation wavelength.

Graphical abstract: Efficient photosensitized energy transfer and near-IR fluorescence from porphyrin–SWNT complexes

Supplementary files

Additions and corrections

Article information

Article type
Paper
Submitted
29 Oct 2007
Accepted
18 Dec 2007
First published
23 Jan 2008

J. Mater. Chem., 2008,18, 1510-1516

Efficient photosensitized energy transfer and near-IR fluorescence from porphyrin–SWNT complexes

J. P. Casey, S. M. Bachilo and R. B. Weisman, J. Mater. Chem., 2008, 18, 1510 DOI: 10.1039/B716649D

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