SCHEDULED MAINTENANCE
Radical rearrangements are important transformations in organic synthesis. The stabilisation of α-nitrogen radicals is shown to be a useful effect for the control of radical rearrangements and is applied to the synthesis of a variety of azabicyclic frameworks. The utility of this method is illustrated in the synthesis of bioactive targets.
D. M. Hodgson and L. H. Winning, Org. Biomol. Chem., 2007, 5, 3071 DOI: 10.1039/B707566A
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