Issue 0, 1974

Preparation of a conjugated tautomer of 1,14:7,8-diethenotetrapyrido-[2,1,6-de:2′,1′,6′-gh:2″,1″,6″-kl:2‴,1‴,6‴na][1,3,5,8,10,12]hexa-azacyclotetradecine and its metal derivatives

Abstract

A hexa-aza-macrocyclic compound of high thermal stability is readily obtained from 2,9-diamino-1,10-phenanthroline by its thermolysis or by its condensation with 2,9-dihalogeno-1,10-phenanthroline. The structure of this macrocycle has been established as a conjugated system of a novel type, related to some extent to porphin and phthalocyanin. The macrocyclic compound forms copper, cobalt, and nickel complexes.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1974, 976-978

Preparation of a conjugated tautomer of 1,14:7,8-diethenotetrapyrido-[2,1,6-de:2′,1′,6′-gh:2″,1″,6″-kl:2‴,1‴,6‴na][1,3,5,8,10,12]hexa-azacyclotetradecine and its metal derivatives

S. Ogawa, T. Yamaguchi and N. Gotoh, J. Chem. Soc., Perkin Trans. 1, 1974, 976 DOI: 10.1039/P19740000976

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