Extensive ab initio calculations have predicted structures and energies for the T-shaped molecules Cl2F2, Cl3F, and Cl4; each is thermodynamically stable to atomisation, but not to dissociation into the appropriate mixture of ClF and Cl2.
C. J. Marsden, J. Chem. Soc., Chem. Commun., 1985, 786 DOI: 10.1039/C39850000786
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