Mass spectrometry of 2,5-diphenylhexa-1,5-dienes provides evidence for the cation-radical Cope rearrangement in the gas phase, in which the reaction directionality is different from that in a thermal process.
H. Ikeda, T. Takasaki, Y. Takahashi and T. Miyashi, J. Chem. Soc., Chem. Commun., 1993, 367 DOI: 10.1039/C39930000367
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