Issue 6, 1994
From the journal:

Journal of the Chemical Society, Faraday Transactions

Chemiluminescent reaction of oxygen atoms with dimethyl disulfide and dimethyl sulfide

Ubaradka B. Pavanaja,   Hari P. Upadhyaya,   Avinash V. Sapre,   Kuchimanchi V. S. Rama Rao  and  Jai P. Mittal  

Abstract

Broad chemiluminescence spectra in the range 240–460 nm with a sharp peak at 308.5 nm are obtained from the reaction between oxygen atoms [O(3P)] with dimethyl disulfide (DMDS) and dimethyl sulfide (DMS). The emitting species are identified as OH (A2Σ+) and SO2(3B, 1B). The photon yields are found to be 3.3 × 10–6 and 4.4 × 10–6 for DMDS and DMS, respectively. Computer simulations were carried out to elucidate the reaction mechanism.

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Article information

DOI
https://doi.org/10.1039/FT9949000825
Article type
Paper

J. Chem. Soc., Faraday Trans., 1994,90, 825-829

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Chemiluminescent reaction of oxygen atoms with dimethyl disulfide and dimethyl sulfide

U. B. Pavanaja, H. P. Upadhyaya, A. V. Sapre, K. V. S. R. Rao and J. P. Mittal, J. Chem. Soc., Faraday Trans., 1994, 90, 825 DOI: 10.1039/FT9949000825

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