SCHEDULED MAINTENANCE
Simple and efficient syntheses have been developed for the cytotoxic dinorditerpenoids, (±)-deoxofaveline 1, (±)-faveline methyl ether 2 and (±)-faveline 3, having a hexahydrodibenzo[a,d]cycloheptene ring system, through the enolizable tricyclic ketone mixture 12 and 13, prepared from the easily accessible 2-arylethyl-3,3-dimethylcyclohexanone 7.
A. K. Ghosh, C. Mukhopadhyay (née Ray) and U. R. Ghatak, J. Chem. Soc., Perkin Trans. 1, 1994, 327 DOI: 10.1039/P19940000327
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