Issue 5, 1997
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

The kinetically-controlled Cope rearrangement of 2,5-bis(4-methoxyphenyl)hexa-1,5-dienes induced by photosensitised electron transfer

Hiroshi Ikeda,   Akito Ishida,   Toshihiko Takasaki,   Sachiko Tojo,   Setsuo Takamuku  and  Tsutomu Miyashi  

Abstract

The photoinduced electron-transfer Cope rearrangement of (E,E)-3,6-bis(4-methoxyphenyl)octa-2,6-diene (E,E)-1 is kinetically controlled and affords quantitatively the thermodynamically less stable (±)-3,4-dimethyl-2,5-bis(4-methoxyphenyl)hexa-1,5-diene (±)-1 at -80 °C in sharp contrast to the thermodynamically-controlled thermal Cope rearrangement.

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Article information

DOI
https://doi.org/10.1039/A701043E
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1997, 849-850

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The kinetically-controlled Cope rearrangement of 2,5-bis(4-methoxyphenyl)hexa-1,5-dienes induced by photosensitised electron transfer

H. Ikeda, A. Ishida, T. Takasaki, S. Tojo, S. Takamuku and T. Miyashi, J. Chem. Soc., Perkin Trans. 2, 1997, 849 DOI: 10.1039/A701043E

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