The diastereoselectivities in nucleophilic additions to bicyclo[2.2.2]octan-2-ones can be modulated by distal endo-substituents; both orbital and electrostatic interactions contribute to the observed stereoselectivity.
G. Mehta, F. A. Khan, B. Ganguly and J. Chandrasekhar, J. Chem. Soc., Chem. Commun., 1992, 1711 DOI: 10.1039/C39920001711
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