Issue 0, 1973
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Synthetic studies on terpenoids. Part XVI. Synthesis of 3β,17-diacetoxyphyllocladen-15-one

Debabrata Mukherjee,   Sunil Kumar Mukhopadhyay,   Kumur Kanti Mahalanabis,   Amitabha Das Gupta  and  Phanindra Chandra Dutta  

Abstract

A stereoselective synthesis of 3β,17-diacetoxyphyllocladen-15-one (XIX) from ethyl 5,5-ethylenedioxy-2-oxo-cyclohexanecarboxylate proceeding in ten stages via methyl 13,13-ethylenedioxy-3-oxopodocarpa-5,9(11)-diene-8β-carboxylate (V) and methyl 3β-hydroxy-13-oxopodocarpane-8β-carboxylate (XII) is described. The ester (XII) has been correlated with a known degradation product from phyllocladene. Some by-products from the hydrogenation of the diene (V) are discussed.

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Article information

DOI
https://doi.org/10.1039/P19730002083
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1973, 2083-2088

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Synthetic studies on terpenoids. Part XVI. Synthesis of 3β,17-diacetoxyphyllocladen-15-one

D. Mukherjee, S. K. Mukhopadhyay, K. K. Mahalanabis, A. D. Gupta and P. C. Dutta, J. Chem. Soc., Perkin Trans. 1, 1973, 2083 DOI: 10.1039/P19730002083

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