Issue 27, 2009

Oxygen isotopic exchange in an MnIIIMn3IV-oxo cubane

Abstract

The rate and activation parameters for oxygen exchange of the μ3-oxo bridges in a manganese tetranuclear cluster with H218O have been measured by ESI-MS; the observed ΔS of −146 ± 22 J K−1.mol−1 is consistent with the expected associative mechanism of substitution.

Graphical abstract: Oxygen isotopic exchange in an MnIIIMn3IV-oxo cubane

Supplementary files

Article information

Article type
Communication
Submitted
27 Mar 2009
Accepted
05 May 2009
First published
15 May 2009

Dalton Trans., 2009, 5278-5280

Oxygen isotopic exchange in an MnIIIMn3IV-oxo cubane

C. A. Ohlin, R. Brimblecombe, L. Spiccia and W. H. Casey, Dalton Trans., 2009, 5278 DOI: 10.1039/B906169J

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