Issue 28, 2010
From the journal:

Dalton Transactions

A new functionalized mesoporous matrix supported Pd(ii)-Schiff base complex: an efficient catalyst for the Suzuki–Miyaura coupling reaction†

Koushik Dhara,*a   Krishanu Sarkar,b   Dipankar Srimani,c   Subrata Kumar Saha,d   Pabitra Chattopadhyaye  and  Asim Bhaumik*f  

* Corresponding authors

a Department of Chemistry, Sambhu Nath College, Labpur, Birbhum, West Bengal, India
E-mail: koushikdhara@rediffmail.com
Fax: +913324732805
Tel: +919433125327

b Department of Chemistry, Netaji Mahavidyalaya, Arambagh, Hooghly

c Department of Organic Chemistry, Indian Association for the Cultivation of Science, Kolkata, India

d Department of Physics, Sambhu Nath College, Labpur, Birbhum, West Bengal, India

e Department of Chemistry, Burdwan University, Golapbug, Burdwan, West Bengal, India

f Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata, India
E-mail: msab@iacs.res.in

Abstract

A new Pd(II) bounded 2D-hexagonally ordered functionalized MCM-41 type material (IV) has been synthesized. Functionalization was carried out by the anchoring of 3-aminopropyltriethoxysilane in the MCM-41 type mesoporous material, followed by grafting with 2,6-diacetylpyridine (DAP) to give a N3-type Schiff base chelating attachment for the Pd(II) species. Fourier transform infrared (FTIR), powder X-ray diffraction (PXRD) and high resolution transmission electron microscopy (HRTEM) studies have been used to characterize the material. Material IV behaves as a highly active catalyst towards Suzuki–Miyaura cross-coupling reaction for the synthesis of biaryl organics. In addition, IV acts as a true heterogeneous catalyst in coupling reaction. It was found that this catalyst is highly efficient and recyclable towards Suzuki–Miyaura reaction with high turn over frequencies. X-Ray photoelectron spectroscopic (XPS) analysis was employed to understand the oxidation state of the palladium atom in the catalyst (IV) and its loading in the material.

Graphical abstract: A new functionalized mesoporous matrix supported Pd(ii)-Schiff base complex: an efficient catalyst for the Suzuki–Miyaura coupling reaction

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Article information

DOI
https://doi.org/10.1039/C003142A
Article type
Paper
Submitted
15 Feb 2010
Accepted
07 May 2010
First published
07 Jun 2010

Dalton Trans., 2010,39, 6395-6402

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A new functionalized mesoporous matrix supported Pd(II)-Schiff base complex: an efficient catalyst for the Suzuki–Miyaura coupling reaction

K. Dhara, K. Sarkar, D. Srimani, S. K. Saha, P. Chattopadhyay and A. Bhaumik, Dalton Trans., 2010, 39, 6395 DOI: 10.1039/C003142A

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