Issue 24, 2010
From the journal:

Chemical Communications

Rhodium-catalyzed tandem nucleophilic addition/bicyclization of diyne-enones with alcohols: a modular entry to 2,3-fused bicyclic furans†

Wanxiang Zhaoa  and  Junliang Zhang*ab  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N, Zhongshan Road, Shanghai 200062, P. R. China
E-mail: jlzhang@chem.ecnu.edu.cn
Fax: (+86) 21-6223-5039

b State key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, P. R. China

Abstract

A novel, efficient and atom-economic Rh-catalyzed stereoselective tandem nucleophilic addition/bicyclization for the synthesis of 2,3-fused bicyclic furans from readily available acyclic diyne-enones and alcohols has been developed.

Graphical abstract: Rhodium-catalyzed tandem nucleophilic addition/bicyclization of diyne-enones with alcohols: a modular entry to 2,3-fused bicyclic furans

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Article information

DOI
https://doi.org/10.1039/C000883D
Article type
Communication
Submitted
13 Jan 2010
Accepted
09 Apr 2010
First published
10 May 2010

Chem. Commun., 2010,46, 4384-4386

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Rhodium-catalyzed tandem nucleophilic addition/bicyclization of diyne-enones with alcohols: a modular entry to 2,3-fused bicyclic furans

W. Zhao and J. Zhang, Chem. Commun., 2010, 46, 4384 DOI: 10.1039/C000883D

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