Issue 18, 2010
From the journal:

Dalton Transactions

Synthesis of 2-acylfurans from 3-(1-alkynyl)-2-alken-1-ones via the oxidation of gold–carbene intermediates by H2O2†

Tao Wanga  and  Junliang Zhang*a  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N. Zhongshan Road, Shanghai, China
E-mail: jlzhang@chem.ecnu.edu.cn
Fax: (86)-21-6223-5039

Abstract

An efficient approach to 2,4,5-trisubstituted 2-acylfurans is described: treating 3-(1-alkynyl)-2-alken-1-ones with AuCl3 in DCM at rt in the presence of H2O2 afforded good yields of 2-acylfurans.

Graphical abstract: Synthesis of 2-acylfurans from 3-(1-alkynyl)-2-alken-1-ones via the oxidation of gold–carbene intermediates by H2O2

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Article information

DOI
https://doi.org/10.1039/C0DT00024H
Article type
Communication
Submitted
11 Dec 2009
Accepted
05 Mar 2010
First published
08 Apr 2010

Dalton Trans., 2010,39, 4270-4273

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Synthesis of 2-acylfurans from 3-(1-alkynyl)-2-alken-1-ones via the oxidation of gold–carbene intermediates by H2O2

T. Wang and J. Zhang, Dalton Trans., 2010, 39, 4270 DOI: 10.1039/C0DT00024H

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