Issue 14, 2008
From the journal:

Dalton Transactions

[Re2(µ-1,2,4-triazolate)2(µ-OH)(CO)6] −: a novel metalloligand for the construction of flexible porous coordination networks†

Elisa Barea,*a   Antonio Rodríguez-Diéguez,b   Jorge A. R. Navarro,c   Giuseppe D′Alfonso*a  and  Angelo Sironi*b  

* Corresponding authors

a Dipartimento di Chimica Inorganica, Metallorganica e Analitica, Università degli Studi di Milano and ISTM-CNR, Via Venezian 21, Milano, Italy
E-mail: ebaream@ugr.es, giuseppe.dalfonso@unimi.it
Fax: +39 0250 314405
Tel: +39 0250 314351

b Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Università degli Studi di Milano and ISTM-CNR, Via Venezian 21, Milano, Italy
E-mail: angelo.sironi@unimi.it, antonio5@ugr.es
Fax: +39 0250 314454
Tel: +39 02 50314448

c Departamento de Química Inorgánica, Universidad de Granada, Av. Fuentenueva S/N, Granada, Spain
E-mail: jarn@ugr.es
Fax: +34 9582 48526
Tel: +34 9582 48093

Abstract

The [Re2(µ-trz-κN1:κN2)2(µ-OH)(CO)6]− (trz = 1,2,4-triazolate) organometallic anion reacts with Ag+ to afford a 2D organometallic/coordination network, [Ag{Re2(µ3-trz-κN1:κN2:κN4)2(µ3-OH)(CO)6}]n·4nCH3OH, which shows dynamic structural changes triggered by solid–liquid guest exchange processes.

Graphical abstract: [Re2(µ-1,2,4-triazolate)2(µ-OH)(CO)6] −: a novel metalloligand for the construction of flexible porous coordination networks

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Article information

DOI
https://doi.org/10.1039/B800591E
Article type
Communication
Submitted
14 Jan 2008
Accepted
29 Jan 2008
First published
19 Feb 2008

Dalton Trans., 2008, 1825-1827

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[Re2(µ-1,2,4-triazolate)2(µ-OH)(CO)6] −: a novel metalloligand for the construction of flexible porous coordination networks

E. Barea, A. Rodríguez-Diéguez, J. A. R. Navarro, G. D′Alfonso and A. Sironi, Dalton Trans., 2008, 1825 DOI: 10.1039/B800591E

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